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Titanium, trichloro

Chlorodialkoxy(cyclopentadicnyl)titanium(IV) derivatives are obtained from trichloro(i75-cy-clopentadicny])titanium34 by reaction of the appropriate alcohols in the presence of a tertiary amine35. [Pg.404]

Preparative Methods see Trichloro(cyclopentadienyl)titanium. Handling, Storage, and Precautions best handled as stock solution either in Et20 (ca. 0.1 M) or toluene (ca. 1.5 M), which must be protected from moisture and UV light. If handled under an inert atmosphere (argon), such solutions can be stored in a refrigerator (8 °C) for several months (possibly much longer) without deterioration. Reactions should be carried out in dry equipment and with absolute solvents under Ar or N2. [Pg.189]

TADDOLate (If) can be obtained from Trichloro-(cyclopentadienyl)titanium and TADDOL (2), with removal ofHCl (eq I). ... [Pg.289]

Cl303ScC,2H24, Scandium(III), trichloro-tris(tetrahydrofuran)-, 21 139 Cl303TiCi2H24, Titanium(III), trichloro-tris(tetrahydrofuran)-, 21 137 CI3O3VC12H24, Vanadium(III), trichlorotris-(tetrahydrofuran)-, 21 138 CLPr, Praseodynium chloride, 22 39 CIsSbCuHio, Antimony(V), trichlorodi-phenyl-, 23 194... [Pg.253]

The alkyl transfer properties of dialkyl zinc reagents have been studied in the reaction of Zn[CH(SiMe3>2]2 with TiCU- The monoalkyl trichloro titanium complex TiCl3[CH(SiMe3)2] was obtained in 83% yield.10... [Pg.325]

The synthesis of a range of mono-Cp -arene trichloro titanium complexes (Scheme 147) has been described. An evaluation of the effect of variations on the pendant arene group, the bridge between the Cp and the arene group and... [Pg.383]

The tetrahydrofluorenyl trichloro titanium compound (Scheme 180) has been prepared by using the dehalosilylation procedure and has been evaluated as a catalyst for styrene polymerization in the presence of MAO as co-catalyst. Syndiotactic polystyrene is obtained with similar characteristics to those reported for other substituted indenyl trichloro titanium derivatives.403,412... [Pg.396]

Trichloro cyclopenta[l]phenanthrene titanium complexes (Scheme 183) have been synthesized. The crystal structure of the 2-methyl-substituted derivative has been determined by X-ray diffraction. In the presence of MAO, these complexes are highly active pre-catalysts for the syndiotactic polymerization of styrene. The 2-phenyl-substituted complex exhibits especially high catalytic activity.416... [Pg.397]

See other pages where Titanium, trichloro is mentioned: [Pg.323]    [Pg.329]    [Pg.317]    [Pg.321]    [Pg.440]    [Pg.323]    [Pg.329]    [Pg.317]    [Pg.321]    [Pg.440]    [Pg.24]    [Pg.44]    [Pg.50]    [Pg.67]    [Pg.105]    [Pg.122]    [Pg.27]    [Pg.147]    [Pg.632]    [Pg.14]    [Pg.41]    [Pg.46]    [Pg.166]    [Pg.231]    [Pg.361]    [Pg.361]    [Pg.382]    [Pg.384]    [Pg.384]    [Pg.387]    [Pg.388]    [Pg.389]    [Pg.390]    [Pg.391]    [Pg.392]    [Pg.394]    [Pg.395]   
See also in sourсe #XX -- [ Pg.16 , Pg.97 ]

See also in sourсe #XX -- [ Pg.16 , Pg.97 ]

See also in sourсe #XX -- [ Pg.16 , Pg.97 ]

See also in sourсe #XX -- [ Pg.97 ]

See also in sourсe #XX -- [ Pg.16 , Pg.97 ]



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