Titanium oxide phosgene

As [TiClg] " had previously been employed as an electrochemical marker for the presence of oxide in these ionic liquids (it reacts with impurities to generate [TiOCI.,] the complete conversion of [TiOCl.,] to [TiClg] demonstrates that not only did the phosgene remove all the oxide ion from the titanium(IV) species, it also removed it from the liquid itself cf. Section 9.4.3 [1977a]. 

Although the basic reaction of titanium(IV) oxide with phosgene at 400 "C was reported in 1911 to give titanium(IV) chloride [360] ... 

Fig. 9.10 The rate of chlorination of titanium(IV) oxide by phosgene as a function of...

ARCTON (75-46-7) Violent reaction with alkaline earth and alkali metals. Reacts violently with aluminum oxide at elevated temperatures, producing hydrogen chloride and phosgene vapors. Incompatible with beryllium, decaborane, diborane, difluoromethylene dihypofluorite, fluorine, lithium, magnesium, potassium, potassium acetylene-1,2-dioxide, potassium acetylene-1,2-dioxide, potassium sodium alloy, sodium amide, titanium, uranium hydride, zinc. Attacks aluminum, magnesium, zinc, and their alloys. 

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