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The titanium methylidene interacts with the carbonyl carbon-oxygen double bond in a sequence that is believed to resemble the metathesis process. With the metallacycle (4), a titanium oxametallacycle is believed to be formed, which then decomposes to generate the new carlxm-carbon double bond and a titanium-oxygen product. The driving force for the reaction has been attributed to the oxophilicity of titanium (equation 18). ... [Pg.1122]

See other pages where Titanium oxametallacycles is mentioned: [Pg.517] [Pg.517] [Pg.517] [Pg.517]