Titanium complexes with hydride ligands

Binding energy, pentacarbonyliron, 6, 3 Binuclear complexes bis-Cp titanium halides, 4, 522 with Ni-M and Ni-C cr-bonds heterometallic clusters, 8, 115 homometallic clusters, 8, 111 Binuclear dicarbonyl(cyclopentadienyl)hydridoiron complexes, with rand C5 ligands, 6, 178 Binuclear iridium hydrides, characteristics, 7, 410 Binuclear monoindenyl complexes, with Ti(IV), 4, 397 Binuclear nickel(I) carbonyl complexes, characteristics, 8, 13 Binuclear osmium compounds, with hydrocarbon bridges without M-M bonds, 6, 619... 

Ethane- and propane-1,2-dithiolato Cp titanium derivatives have been reported. They are reduced by boron and tin hydrides.1013,1014 Mono-Cp titanium(iv) sulfido complexes have been made by treatment of CpTiCl3 with dithiols in the presence of donor ligands such as imidazole or PMe3 under different reaction conditions (Scheme 418).1015 The structures of the compounds have been reported. Electrochemical studies suggest that these compounds are formed through a radical mechanism.1016... 

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