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Thiolates terminal ligands

Several other tetranuclear iron-sulfur cluster compounds of general formula [Fc4S4X4]" ", in which X is a non-thiolate terminal ligand, have been studied in some detail. These include systems in which X = Cl, NO and dithiolene. The structure of the dianion [Fe4S4Cl4] " has been... [Pg.240]

Alkyne adducts of M0CI4 were reported in 1973 by Greco et al. (221). An array of monomeric (222) and dimeric (223) d2 W(IV) complexes related to [W(C1C=CC1)C15] has been reported by Dehnicke. Schrock has prepared Mo(IV) and W(IV) alkyne derivatives with halide, alkoxide (224), and thiolate (225) ligands present. Other d2 monomers with alkyne ligands have terminal oxo (226,227), nitrene (228), and sulfido (61) ligands. [Pg.92]

The tripalladium mixed-valence Pd3(2/3) and Pd3(4/3), Pd(II) and Pd(0) clusters may be formed with a range of phosphines, isocyanides, or carbonyls as terminal ligands and carbonyls, nitrosyls, isocyanides, sulfur dioxide, phosphides, phosphines or diphosphines, halides, thiolates as doubly or triply bridging ligands. These clusters exhibit a wide range of steric and electronic environments. [Pg.500]

See other pages where Thiolates terminal ligands is mentioned: [Pg.36]    [Pg.36]    [Pg.240]    [Pg.36]    [Pg.36]    [Pg.240]    [Pg.62]    [Pg.444]    [Pg.255]    [Pg.261]    [Pg.267]    [Pg.274]    [Pg.205]    [Pg.260]    [Pg.349]    [Pg.594]    [Pg.1428]    [Pg.143]    [Pg.148]    [Pg.151]    [Pg.157]    [Pg.528]    [Pg.630]    [Pg.162]    [Pg.77]    [Pg.77]    [Pg.98]    [Pg.4122]    [Pg.305]    [Pg.629]    [Pg.630]    [Pg.70]    [Pg.594]    [Pg.56]    [Pg.497]    [Pg.331]    [Pg.309]    [Pg.4121]    [Pg.240]    [Pg.158]    [Pg.163]    [Pg.1174]    [Pg.3267]    [Pg.3694]    [Pg.6774]    [Pg.6775]    [Pg.13]    [Pg.60]    [Pg.68]    [Pg.84]   
See also in sourсe #XX -- [ Pg.2 , Pg.527 ]



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