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Thiolate bulky aromatic

Although the hydrazido(2 —) ligand has the same formal charge as the oxo group, isoelectronic oxo and hydrazido species exhibit very different redox properties. Thus MoOC14 is rapidly reduced by bulky aromatic thiolates to the Mov species [MoO(SAr)4] 496 whereas no reduction occurs with MoCl4(NNMePh), the Movl species [Mo(NNMePh)(SPh)4] being formed.497... [Pg.148]


See other pages where Thiolate bulky aromatic is mentioned: [Pg.299]    [Pg.168]    [Pg.1250]    [Pg.417]    [Pg.430]    [Pg.435]    [Pg.451]    [Pg.218]    [Pg.794]    [Pg.3089]    [Pg.418]    [Pg.429]    [Pg.451]    [Pg.914]    [Pg.218]    [Pg.172]    [Pg.619]    [Pg.334]   
See also in sourсe #XX -- [ Pg.40 ]




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