Thiocyanates synthesis

Pyrimidin-4-yl thiocyanate, 6-methyl-2-methylthio-synthesis, 3, 95 Pyrimidinyl thiocyanates synthesis, 3, 95 Pyrimidobenzimidazoles synthesis, 5, 438... 

Octyl thiocyanate synthesis/isomerization, microwaves in, 16 566 Octyltriethoxysilane, as silylating agent, 22 697... 

MONOSACCHARIDE ISOTHIOCYANATES AND THIOCYANATES SYNTHESIS, CHEMISTRY, AND PREPARATIVE APPLICATIONS... 

Pyrimidinones, 5-methylsulfonyl-synthesis, 3, 138 Pyrimidin-2-ones IR spectra, 3, 64 Pyrimidin-2( 1H)-ones acidic pKa, 3, 60 alkylation, 3, 90 nitration, 3, 69 pKa> 3, 60 reduction, 3, 75 synthesis, 3, 132 Pyrimidin-4(3/7)-ones alkylation, 3, 90 synthesis, 3, 132 thiation, 3, 89 Pyrimidinophanes synthesis, 7, 768, 774 Pyrimidinopurinophanes synthesis, 7, 766 Pyrimidin-2-yl thiocyanate synthesis, 3, 95... 

Silicon tetraisothiocyanate and methylsilicon isothiocyanates (includes silver thiocyanate), synthesis 7... 

Z.K.Witczak, Monosaccharide Isothiocyanates and Thiocyanates Synthesis, Chemistry and Preparative Applications, Adv.Carbohyd. Chem.and Biochem., 1986, 4 4, 91. 

Uranium(lV) oxalate, synthesis 45 Potassium tetraoxalatouranate (IV), synthesis 46 Barium thiocyanate, synthesis 5 Potassium octacyanomolybdate (IV) 2-hydratc, synthesis 43 Bis(lV,lV -disallcylalethylenedia-mine)-/t-aquodicobalt(II), synthesis 53... 

Cyanamide, synthesis 9 Dicyanodiamide, synthesis 10 Barium thiocyanate, synthesis 5 Potassium ootacyanomolybdate (IV) 2-hydrate, synthesis 43 Zirconium hafnium phosphates, synthesis IOC... 

Barium thiocyanate, synthesis 5 Ammonium dithiocarbamatc, synthesis 12... 

G. Sotgiu, M. Zambianchi, G. Barbarella, F. Aruffo, F. Cipriani and A. Ventola, Rigid-core fluorescent oligothiophene-5, 5 -dioxide iso thiocyanates. Synthesis, optical characterization and conjugation to monoclonal antibodies, J. Org. Chem., 68, 1512-1520 (2003). 

A full paper detailing the conversion of primary alkylamines into the corresponding thiocyanates has appeared,and this important contribution to thiocyanate synthesis has now been extended to include aromatic derivatives. Thus, the readily prepared (56) reacts, in refluxing ethanol, with arylamines to give (57), which are smoothly pyrolysed to aryl thiocyanates in preparatively useful yields (Scheme 55). 

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