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Thioacyl fluoride

The thermal and chemical stability of the chlorof uorothioacetyl fluoride copolymers are considerably better than the homopolymer. It has been suggested that these effects are associated with ability of the side group to interrupt chain decomposition. When the chain degrades back to a thioacyl unit, the reaction... [Pg.96]

Convenient syntheses for ammonium311 320 and alkali metal salts (from trimethylsilyl dithiocarboxylates and alkali metal fluorides),321,322 useful for preparative purposes of their metal complex and organometallic derivatives, are now available. The reactions of bis(thioacyl)disul-fanes, [RC(S)S]2 (R = Pr , Ph, p-MeOC6H4, p-Tol, p-ClC6H4, CK-C10H7) with secondary amines yield substituted ammonium dithiocarboxylates, [R NHJP CSJ.323... [Pg.364]

Die sich aus Thiocarbonyl-halogeniden z. B. unter UV-Bestrahlung oder beim Stehen leicht bildenden 2,4-Dichlor-l,3-dithietane17(zur thermolytischen Riickreaktion s.19) liefern mit Antimon(V)-fluorid bei anschlieBender Pyrolyse die entsprechenden Thioacyl-fluori-de17 ... [Pg.619]

See other pages where Thioacyl fluoride is mentioned: [Pg.1498]    [Pg.72]    [Pg.132]    [Pg.1498]    [Pg.72]    [Pg.132]    [Pg.241]    [Pg.307]    [Pg.452]    [Pg.425]   
See also in sourсe #XX -- [ Pg.132 ]

See also in sourсe #XX -- [ Pg.132 ]



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1- Thioacyl

Thioacylation

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