Thiabendazole metal complexes

Tetraaza macrocycles nickel complexes, S Tetragonality copper(II) complexes, 603 Theophylline cadmium complexes, 957 Thermolysin zinc, 1006 Thiabendazole metal complexes, 951 Tollen s reagent, 780 Transcription DNA polymerases, 1007 Trans effect... 

Thiabendazole is a benzimidazole compound. Although it is a chelating agent that forms stable complexes with a number of metals, including iron, it does not bind calcium. 

Complexes of the stoichiometry [ML3] [C104]2 [L = thiabendazole (65)] contain the metal in an octahedral coordination with the chelating ligand coordinated via the nitrogens of the imidazole and thiazole rings.465... 

Thiabendazole, USP. 2-(4-Thiazolyl)bcn/imida/.olc (Mintezol) occurs as a white crystalline substance that is only. slightly soluble in water but is soluble in strong mineral acids. Thiabendazole is a basic compound with a pK.., of 4.7 that forms complexes with metal ions. 

The structure of (9-methyladenine)ZnCl2 is polymeric each zinc ion is tetrahedrally co-ordinated to two chlorine atoms (Zn—Cl = 2.22 AX and to N(l) and N(7) of neighbouring adenine moieties (Zn—N = 2.05 A).Complexes of the stoicheiometry [ML3][C104]2[L = thiabendazole (1)] contain the metal in an octahedral co-ordination with the chelating ligand co-ordinated via the nitrogens of the imidazole and thiazole rings. 

The active substance has a systemic effect. It is translocated (Weinke et ai, 1969), but more slowly than benomyl or MBC (Wang et ai. 1971 Ben-Arie, 1975). The metal salt complexes of thiabendazole also have a fungicidal effect (Miller et ai,... 

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