Thermodynamic Relations for the Calculation of Solid-Liquid Equilibria

Thermodynamic Relations for the Calculation of Solid-Liquid Equilibria 

As for all other phase equilibria, the calculation of SLE starts from the isofugacity condition (Eq. (8.1))  

The fugacity can be described with the help of activity coefficients and standard fugacities for the liquid phase L and the solid phase S. 

To be able to calculate the solubility in the liquid and solid phase, only the activity coefficients and and the ratio of the standard fugacities of the 

4) The vapor pressure of the hypothetical liquid can be obtained by extrapolation of the vapor pressure curve to temperatures 

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C. 7 Thermodynamic Relations for the Calculation of Solid-Liquid Equilibria 413... 

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