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The Stereochemical Consequences of Coulomb Polarization in Ground State Molecules

The strategy for giving prominence to monoelectronic polarization involves now the following two steps. [Pg.514]

1) Thed. j matrix elements become small, in absolute magnitude. [Pg.514]

2) The energy requirement for local fragment excitation is reduced. [Pg.514]

H-BOUND FOUR-ELECTRON-THREE-ORBITAL SYSTEM [Pg.515]

By contrast, if C and L are made up of strong overbinders, then polarization will play a secondary role and bonding will occur primarily through the strong CT interaction of all CW s, and, of course, through spin pairing in 2 and [Pg.516]


Chapter 20. The Stereochemical Consequences of Coulomb Polarization In Ground State Molecules. [Pg.512]




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Coulombic states

Ground State of

Ground state molecules

Molecule polarity

Molecules polar molecule

Polarity in molecules

Polarity of the molecule

Polarization of molecule

Polarization state

Polarized molecules

State of.polarization

Stereochemical consequences

The ground state

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