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The steady nonequilibrium space charge in concentration polarization at a permselective homogeneous interface

The steady nonequilibrium space charge in concentration polarization at a permselective homogeneous interface [2]. It [Pg.170]

In order to trace this phenomenon in more detail and to investigate some properties of the space charge that forms, consider the following space charge analogue of (4.4.1) [Pg.170]

Here j is again an unknown integration constant (dimensionless cation flux, electric current density) to be determined from the boundary conditions (5.3.8). [Pg.171]

Let us point out first that the system in (5.3.6), (5.3.7) can be integrated exactly in terms of the Painleve transcendents of the second kind. Indeed, by going back to (5.3.1)-(5.3.3) we observe that adding (5.3.1), (5.3.2) and substituting equation yields [Pg.171]

Furthermore, after another integration we obtain, using (5.3.6b), 53 9) [Pg.171]




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A-space

Charge at interfaces

Concentration polarization

Concentration space

Interface concentration

Interface polarization

Interface polarized

Interface space charge

Interfaces charged

Nonequilibrium

Nonequilibrium polarization

Permselective

Permselectivities

Permselectivity

Polar interface

Polarity charge

Polarity/polarization interface

Polarization charge

Space charging

Space-charge

The Interface

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