The Main Data on MMC Topochemistry

The distribution of polymer-bound metal ions is not homogeneous. Even at the low concentrations of bound complexes, the formation of three types of complexes is observed. 

Aggregations of the cluster type, in which complexes of unbound paramagnetic metals occur between each other, in which F 7 A. 

Clusters in which there is a strong exchange interaction (i.e., exchange-bound clusters that are caused by chemical bonds as polynuclear complexes). 

The peculiarity of macrocomplexes topochemistry influences their catalytic properties. As a rule, the extremal dependence of the specific catalytic activity on the surface density of bond metal complexes in all catalytic processes (for example, polymerization, hydrogenation, md oxidation) is observed. However, their kinetic behavior correlates with neither Cjsoi nor Cdust of the complexes. This area too deserves further investigtion.  

METAL-CONTAINING POLYMERS OBTAINED BY COPOLYMERIZATION OF METAL-CONTAINING MONOMERS 

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