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The Lack of Exchange in Double-Label Experiments

Similar results were obtained with PBMA and PMMA tagged with tri-ethylsilyl and trimethylsilyl groups. However here Bywater has noted that the triethylsilyl ended polymer may not be polymerizing significantly during [Pg.18]

In double-labeling experiments using PMMA of two different molecular weights Quirk obtained partial exchange in 2 h [37]. Since the dissociate mechanism demands complete exchange, these experiments support an associative pathway. [Pg.19]


See other pages where The Lack of Exchange in Double-Label Experiments is mentioned: [Pg.18]    [Pg.29]   


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