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The kinetic energy operators of translation, rotation and vibrations

4 THE KINETIC ENERGY OPERATORS OF TRANSLATION, ROTATION AND VIBRATIONS [Pg.245]

35) may serve to construct the corresponding kinetic energy operator for a polyatomic molecule. There is no problem (see Chapter 1) with the translational [Pg.245]

There is a problem with the rotational term. A rigid body (the equilibrium atomic positions are used), e.g., the benzene molecule, rotates, but due to symmetry it may have some special axes characterizing its moment of inertia. The moment of inertia represents a tensor of rank 3 with the following components  [Pg.245]

Izz- Then the classical expression for the kinetic energy of rotation [Pg.245]

Goldstein, Classical Mechanics , 2nd edition, Addison-Wesley, 1980. [Pg.245]


The kinetic energy operators of translation, rotation and vibrations... [Pg.218]




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Energy operator

Energy rotational

Energy rotational, 78 translational

Energy translational

Energy vibrational

Energy, translation

Kinetic energy of rotation

Kinetic energy operator

Kinetic energy translational

Kinetics translation

Operator kinetic

Operator rotational

Operator translational

Operator vibration-rotational

Rotating energy

Rotating operation

Rotation energy

Rotation kinetic energy

Rotation of the

Rotation operation

Rotation operator

Rotation-vibration

Rotational energy, and

Rotational kinetic energy operator

Rotational operations

Rotational vibrations

Rotational-translational

Rotational-vibrational

Translation and

Translation and rotation

Translation operator

Translational vibrations

Vibrating rotator

Vibration and Operation

Vibration energy

Vibrational kinetic energy

Vibrational, rotational, and

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