The First Step towards True Charge Transfer

The First Step towards True Charge Transfer 

The precise values of y for variorrs adsorbates on platinum single crystals are available now (see examples in Refs 114, 147), and it is probably a challenge to corrrpare their behavior with two 

To determine (c), one should treat a set of adsorption curves for a pH interval as wide as possible. The accuracy of this treatment is not too high, but the reliability of final X and Y values can be checked by comparison with the ratio X X+Y) determined independently from another type of data.  

Further quantitative analysis is hardly reasonable, as the data for comparison should be obtained at exactly one and the same electrode and solution. At this stage we can only conclude from this comparison that the tme charge transfer can be used for ca//- 

Phenomenological model of effective charge transfer coefficients is presented in Ref. 196. Its application to available thermodynamic data surely can not result in any tme charge transfer coefficients, but provides independent possibility to estimate differential effects of solution composition on the electrode charge values. General trends agree with the trends going from X and Y analysis. 

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