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The Effective Interaction Between Ions, and Higher-Order Terms

B The Effective Interaction Between Ions, and Higher-Order Terms 387... [Pg.387]

The electrostatic interaction only between monomers with nonzero monopole charges, with or without condensed ions, is considered till now in this work (the third-term in the polymer free energy Fs). Further, Fs considers only the monopole contribution of each ion-pair or ion-triplet. For example, a monomer-Na pair and a monomer-Ba +-Cl triplet would contribute identically to Fs, although they have different electrostatic effects. Similarly, a monomer-Ba pair would be simply treated as a +1 charge, although the pair has additional dipole effects. These additional dipole or higher order multipole effects are critical when the average... [Pg.273]

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Effective interaction

Effective terms

Effects interaction

Higher order effects

Higher-order interactions

Higher-order terms

Interaction terms

Interactive effects

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