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The Belousov-Zabotinsky Reaction

The best studied homogeneous oscillatory reaction involves the oxidation of propanedioic acid (PDA) by bromate in acidified bromide solution, catalysed by Ce(IV). The overall reaction is  [Pg.129]

Reduction of bromate by bromide with the bromination of the acid  [Pg.129]

Add 30 cm concentrated sulphuric acid slowly to 399 cm cooled water and dissolve in the solution 10 g propanedioic acid, 3.9 g potassium bromate and 0.4 g ammonium hexanitrocerate(IV). Add to the solution drops of 0.025 M ferroin indicator ( 14 cm ) to give a visible colour. Stir magnetically and note the change in colour from blue to red. Alternatively, insert a platinum electrode into the solution and dip a calomel electrode through a salt bridge in the solution. Connect the two electrodes to a mV meter and [Pg.129]


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