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Thallium triacetate reaction with alkenes

Acyl esters of vicinal diols are obtained by the reaction of alkenes with metal carboxylates [436]. Lead tetraacetate in acetic acid at 70 °C converts 1,2-dihydronaphthalene to rranj-l,2-diacetoxy-l,2,3,4-tetrahy-dronaphthalene in 72% yield [436]. The reaction is not always stereospecific. Cyclohexene treated with thallium triacetate gives a mixture of diastereomers in varying ratios, depending on reaction conditions, and byproducts as a result of rearrangements (equation 89) [411],... [Pg.74]

See other pages where Thallium triacetate reaction with alkenes is mentioned: [Pg.923]    [Pg.710]    [Pg.92]    [Pg.92]    [Pg.972]   
See also in sourсe #XX -- [ Pg.534 ]

See also in sourсe #XX -- [ Pg.534 ]

See also in sourсe #XX -- [ Pg.7 , Pg.534 ]

See also in sourсe #XX -- [ Pg.7 , Pg.334 ]

See also in sourсe #XX -- [ Pg.534 ]



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Reaction with alkenes

Thallium , reaction

Thallium triacetate

Triacet

Triacetate

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