Thallium triacetate carboxylic acids

Acyl esters of vicinal diols are obtained by the reaction of alkenes with metal carboxylates [436]. Lead tetraacetate in acetic acid at 70 °C converts 1,2-dihydronaphthalene to rranj-l,2-diacetoxy-l,2,3,4-tetrahy-dronaphthalene in 72% yield [436]. The reaction is not always stereospecific. Cyclohexene treated with thallium triacetate gives a mixture of diastereomers in varying ratios, depending on reaction conditions, and byproducts as a result of rearrangements (equation 89) [411],... 

Thallium triacetate, 406 Thallous carboxylates, 410 Thallous ethoxide, 407-411 Thebaine, 330, 331 Thiacyclohexane, 358 Thiazolidine-4-carboxylic acid, 27 Thiele reaction, 7-9, 12, 13 Thiepin-1,1-dioxide, 392 Thioanisole, 99, 311, 324 Thiocarbonates, 105, 106 N,N -Thiocarbonyldiimidazole, 411-412 Thiocyanogen, 105, 440 Thionyl chloride, 176, 395, 410, 412 Thiophenols, 173, 174 Thiophosgene, 412 Thiourea, 157, 412-413 Thymidine, 297, 298 Thymidine 5 -phosphate, 298 Thymine, 370 Tigonin, 136 Tin, 414... 

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See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ ]

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