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Tetren

The kinetics of the reaction is first order in both nitrile complex and azide.909 NaN3 reacts with [Co(tetren)(NCMe)]3+ at pH 5.7 to give the 5-methyltetrazolato complex [Co(tetren)(N4CMe)]2+. The reaction is biphasic, involving the initial rapid formation of the AM-bonded tetrazole followed by the slow linkage isomerization to the N2-bonded complex.907... [Pg.78]

A. trans-BIS(TETRENNICKEL(II))HEXACYANOCHROMIUM(III) CHLORIDE, [Cr(CN)4 CNNi(tetren) 2]Cl... [Pg.147]

To a solution of tetraethylenepentamine pentahydrochloride (tetren 5HC1, Aldrich) (2.24 g 6.0 mmol) dissolved in 20 mL of water is added 1.21 g of sodium hydroxide (30 mmol, 5 equiv). A solution of nickel(II) chloride hexa-hydrate in 10 mL of water (0.95 g, 4.0 mmol) is then slowly added. The mixture is stirred for 20 min before adding dropwise a solution of potassium hexacyano-chromate(lll) (0.325 g, 1 mmol) in a minimum of water. The solution is left... [Pg.147]

B. HEXAKIS(TETRENNICKEL(II))HEXACYANOCHROMIUM(III) PERCHLORATE, [Cr CNNi(tetren) 6][C104]9... [Pg.148]

Cr CNNi(tetren) 6](C104)9 is a red-purple solid, soluble in water-acetonitrile mixtures where the undissociated heptanuclear entity can be identified by electrospray ionization mass spectrometry. IR spectroscopy shows the presence of a unique /cn band at 2146 cm of the bridging cyano ligand and an intense band of the perchlorate anion at cr = 1090 cm The IR spectrum of the C-enriched compound prepared from K3[Cr( CN)6] displays a /cn band at 2103 cm The compound crystallizes in a trigonal system, space group R3, with parameters a = b = 15.274 A and c = 41.549 A. The magnetic properties indicate a ferro-... [Pg.149]

C7H704Rh, Rhodium(I), dicarbonyl(2,4-pentanedionato)-, 34 128 C7HgN4, Bis(l-pyrazolyl)methane, bpm, complex with nickel(ll), 34 139 CgH5FeKN20, Ferrate(ll), carbonyldicyano-(cyclopentadienyl)-, potassium, 34 172 CgH23Ns, Tetraethylenepentamine, tetren, complex with nickel(ll), 34 147, 148 CgH24B2N4, Diborane(4), tetrakis(dimethyl-amino)-, 34 1... [Pg.243]

The complex [Cr(tetren)(H20)]3+, prepared by hydrolysis of [CrCl(tetren) 1C12,... [Pg.814]

The kinetics of displacement of either trien or tetren from their nickel complexes by edta have been investigated.2542,2543... [Pg.219]

See other pages where Tetren is mentioned: [Pg.116]    [Pg.118]    [Pg.120]    [Pg.122]    [Pg.123]    [Pg.77]    [Pg.198]    [Pg.202]    [Pg.267]    [Pg.267]    [Pg.267]    [Pg.267]    [Pg.267]    [Pg.103]    [Pg.316]    [Pg.179]    [Pg.180]    [Pg.67]    [Pg.147]    [Pg.147]    [Pg.147]    [Pg.148]    [Pg.148]    [Pg.148]    [Pg.148]    [Pg.252]    [Pg.154]    [Pg.190]    [Pg.339]    [Pg.339]    [Pg.814]    [Pg.814]    [Pg.814]    [Pg.74]    [Pg.75]    [Pg.683]   
See also in sourсe #XX -- [ Pg.168 ]

See also in sourсe #XX -- [ Pg.111 ]

See also in sourсe #XX -- [ Pg.203 ]



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Tetraethylenepentamine, tetren

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