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Tetraphenylbismuthonium perchlorate

When triphenylbismuth dichloride, ia acetone, is treated with silver perchlorate, ia absolute ethanol, tetraphenylbismuthonium perchlorate [43047-28-5], C24H2QBiC104, is formed (165). If, however, the same reaction is carried out only ia acetone, the following reaction occurs (166) ... [Pg.133]

In some limited solvent systems, a metathetical reaction between triphenyl-bismuth dichloride and silver perchlorate results in the formation of oxybis-(triphenylbismuth) diperchlorate [72JOM(36)323]. This type of compound is only obtained when a mixture of water-benzene is used as the reaction medium. When the same reaction is carried out in absolute ethanol or in pure acetone, tetraphenylbismuthonium perchlorate and acetonyltriphenylbismuthonium perchlorate are obtained as the respective product (Section 3.3.1). [Pg.279]

Tetraphenylbismuthonium nitrate, perchlorate, tetraphenylborate, cyanate, thiocyanate, perchlorate, tetrafluoroborate, hexafluorophosphate and trichloro-acetate have been prepared by this metathesis method [52LA(578)136, 73JCS(D)1394]. Unsymmetrical tetraarylbismuth(V) compounds can be prepared similarly [68LA(720)198]. [Pg.286]

See other pages where Tetraphenylbismuthonium perchlorate is mentioned: [Pg.934]    [Pg.286]    [Pg.296]    [Pg.297]    [Pg.561]    [Pg.934]    [Pg.286]    [Pg.296]    [Pg.297]    [Pg.561]   
See also in sourсe #XX -- [ Pg.5 ]



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