2,4,7,9-Tetraphenyl-1,10-phenanthroline

Iron Iron co-precipitated with tetraphenyl boron/1,10-phenanthroline, precipitate dissolved in ammoniacal ethanol Miscellaneous [568]... 

Through the presence of aromatic or pseudoaromatic groups in the molecule (tetraphenylborate and related derivatives, the tetraphenyl-arsonium ion, cationic triphenylmethane dyes, complexes of o-phenanthroline with divalent nickel or ion, where the hydrophobicity is increased by further substitution by a hydrophobic group on the pseudoaromatic nucleus). 

Although 1,10-phenanthroline could not be induced to react with phenyl lithium, 4,7-dimethyl- and 4,7-diphenyl-1,10-phenanthrolines, as expected, afford the 4,7-dimethyl-2,9-diphenyl and 2,4,7,9-tetraphenyl derivatives, respectively.196... 

Ru(bipy)i Ru(II)-tris-2,2,bipyridiyne Ru(phen) Ru(II)-tris-l,10-phenanthroline Ru(dpp) Ru(II)-tris(4,7-diphenyl)-l,10-phenanthroline PtOEP platinum(II)-octaethylporphyrin PdOEP palladium(II)-octaethylporphyrin PdTPFFP palladium(II)-tetra(pentafluoro-phenyl)porphyrin L 2,4,7,9-tetraphenyl-l,10-phenanthroline py pyridine MP 3-methyl-pentane... 

Ar O = 2,6-di-f-butylphenoxide acac = acetylacetonate bppy = 4-(l-butylpentyl)pyridine cup = cupferron dippe = l,2-bis(diisopropylphosphino)ethane dppe = l,2-bis(diphe-nylphosphino)ethane fee = face-centered cubic = CH(Cp3)2 hep = hexagonal close-packed hexone = methyl isobutyl ketone OEP = octaethylporphyrinogen phen = phenanthroline py = 4-pyrrolidinopyridine tritox = (f-Bu)3CO tbp = BU3PO4 TPP = tetraphenyl-porphyrino-gen trmpe = tris(dimethylphosphinomethyl)ethane. 

---