Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

2,2,6,6-Tetramethylpiperidine-iV-oxyl

Nitroxyl radicals can be oxidized to N-oxo ammonium salts that are themselves useful oxidants for primary and secondary alcohols. Recently, the behavior of different nitroxides as catalysts for alcohol oxidation has been studied by quantum chemical calculations [105]. Generally, 2,2,6,6-tetramethylpiperidine iV-oxyl (TEMPO) (80) is used for the... [Pg.5168]

Shorthand notations such as ET (electron transfer), HAT (hydrogen atom transfer), BDE (bond dissociation energy), NHE (normal hydrogen electrode), CV (cyclic voltammetry), LFP (laser flash photolysis), EPR (electron paramagnetic resonance) and KIE (kinetic isotope effect) will be used throughout the chapter. In addition, recurring chemical compounds such as TEMPO (2,2,6,6-tetramethylpiperidine-Ai-oxyl), HBT (1-hydroxyben-zotriazole), BTNO (benzotriazole-A-oxyl), HPI (iV-hydroxyphthalimide), PINO (phthal-imide-iV-oxyl), NHA (A-hydroxyacetanilide) and a few others will be referred to by means of the capital-letter acronym. [Pg.706]

See other pages where 2,2,6,6-Tetramethylpiperidine-iV-oxyl is mentioned: [Pg.337]    [Pg.95]    [Pg.133]    [Pg.239]    [Pg.228]    [Pg.225]    [Pg.98]    [Pg.114]    [Pg.129]    [Pg.95]    [Pg.133]    [Pg.239]    [Pg.228]    [Pg.225]    [Pg.98]    [Pg.114]    [Pg.4106]    [Pg.190]    [Pg.506]    [Pg.337]    [Pg.129]   


SEARCH



2,2,6,6-Tetramethylpiperidines

2,2,6,6-tetramethylpiperidine-1 -oxyl

Oxyls—

Tetramethylpiperidin

© 2024 chempedia.info