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Tetrahedral copper complexes structure

Figure 17.29 Structure of distorted tetrahedral copper complexes. SP is sparteine-TV./V, mint is maleonitriledithiolate, dmp is 2,9-dimethyl-1,10-phenanthroline, and phen is 1,10-phenan-throline. Reprinted with permission from Ref. 67. Copyright 2005 American Chemical Society. Figure 17.29 Structure of distorted tetrahedral copper complexes. SP is sparteine-TV./V, mint is maleonitriledithiolate, dmp is 2,9-dimethyl-1,10-phenanthroline, and phen is 1,10-phenan-throline. Reprinted with permission from Ref. 67. Copyright 2005 American Chemical Society.
In their pursuit of modeling Type I copper proteins, Kitajima et al. reported112 a rare, tetrahedrally coordinated complex (105), which displayed an EPR spectrum consistent with the presence of the unpaired electron in the dz2 orbital.1 They also isolated a square-pyramidal DMF adduct (complex (106)). They were successful in providing structural proof of a copper(II) complex (trigonal pyramidal) with C6F5S -coordinated complex (107), with CuN3S chromo-phore.113 The X-ray analysis (poor data set) of a closely similar complex with Ph3CS as the... [Pg.768]

A close structural situation is observed for clv-planar palladium 908 (M = Pd) [201] and distorted tetrahedral copper 908 (M = Cu) [242] chelates. The N atom of pyridine substituent is turned out from the metal complex-former in these chelates. [Pg.353]

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Copper complexes structure

Copper structure

Tetrahedral complexes

Tetrahedral copper complexes

Tetrahedral structure

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