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Tert-Butylhydrazine

In addition to the procedure given here for the oxidation of tert-octylamine to nitroso-tert-octane,2 the oxidation may be carried out with m-chloroperoxybenzoic acid or with a solution of peroxyacetic acid in ethyl acetate.4 The lead dioxide oxidation of alkyl hydrazines to alkyl radicals appears to have general application. In addition to tert-butylhydrazine, various secondary alkylhydrazines (e.g., bornylhydrazine and menthylhydrazine) have been used to good effect. The reduction of tri-tert-alkylhydroxyl amine to the di-tert-alkylamine has also been achieved with sodium in ammonia but the insolubility of the hydrophobic substrate makes this procedure difficult. The use of sodium naphthalenide gives higher yields and is more reproducible. [Pg.86]

Aldrich Chemical Company, Inc.) by distillation from 40% KOH (bp 104-107°C). The distillate consists of a mixture of tert-butylhydrazine and water. Upon addition of several grams of KOH pellets, the distillate... [Pg.233]

Additional lead dioxide and/or tert-butylhydrazine may be necessary to complete the reaction. [Pg.233]

See other pages where Tert-Butylhydrazine is mentioned: [Pg.132]    [Pg.43]    [Pg.44]    [Pg.56]    [Pg.235]    [Pg.267]    [Pg.516]    [Pg.146]    [Pg.87]    [Pg.232]    [Pg.233]    [Pg.233]    [Pg.94]    [Pg.95]    [Pg.239]    [Pg.240]    [Pg.169]    [Pg.170]    [Pg.172]    [Pg.125]   
See also in sourсe #XX -- [ Pg.43 , Pg.44 , Pg.56 ]



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