Tert-Butyl chloroacetate

BUTYL CELL0S0L T ACETATE see BPMOOO n-BUTYL CHLORIDE see BQQ750 BUTYL CHLORIDE pOT) see BQQ750 sec-BUTYL CHLORIDE see CEU250 tert-BUTYL CHLORIDE see BQROOO tert-BUTYL CHLOROACETATE see BQRIOO a-BUTYL-a(4-CHLOROPHENYL)-lH-l,2,4-THIAZOLE-l-PROPANENITRILE see MRW775 tert-BUTYL CHROMATE see BQVOOO... 

C6H11CI02 tert-butyl chloroacetate 107-59-5 423.15 36.552 1,2 8140 C6H11N02 3-cyanopropionaldehyde dimethyl acetal 14618-78-1 481.12 42.073 2... 

A 250 ml round-bottomed flask, under Ar, was charged with 50 ml of Rieke Zn solution (5g at O.lg/ml 76mmol). The flask was cooled between 5 and 10°C using a water bath with a little ice. The tert-butyl chloroacetate was added dropwise over 10 min. The temperature was maintained between 5 and 20°C. After stirring for 2h, the reaction was determined to be complete by GC. The reaction was centrifuged to remove excess Rieke Zn, botded under Ar, and diluted to 100 ml with fresh THF (0.5 M). 

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