Template Condensations at Kinetically Inert Octahedral Metal Centres

2 Template Condensations at Kinetically Inert Octahedral Metal Centres 

What should we do to observe a three-dimensional template effect First, we should choose a reaction type that we know to be effective for the formation of macrocyclic ligands and extend the methodology to a kinetically inert cP or d6 metal centre. Let us reconsider the reaction, that we first encountered in Fig. 6-11. In this reaction, a dioximato complex reacted with BF3 to give the nickel(n) complex of a dianionic macrocycle (Fig. 7-1). 

Metals and Ligand Reactivity, New Edition. Edwin C. Constable Copyright 1996 VCH Verlagsgesellschaft mbH, Weinheim ISBN 3-527-29278-0 

7 The Three-Dimensional Template Effect, Supramolecular Chemistry and Molecular Topology  

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