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Temperature Dependence of AGm and In

From Equation (10.22), when applied to a reaction in solution, we use K, not Kp [Pg.234]

Such behavior is exhibited by the simple chemical reaction [Pg.234]

Very precise, classic, measurements of the ionization constant of acetic acid were made many decades ago [2]. The dependence of In K on temperature is illustrated in Eigure 10.2. As the temperature is increased from 273 K, In K and the degree of ionization increases gradually, reaching a maximum just below 298 K, and then [Pg.234]

When we compare chemical reactions at a fixed temperature, that reaction with the more positive value of AGm is less spontaneous, less capable of progressing from reactants to products. On the other hand, when we compare a given reaction at different temperatures, a temperature with a more positive AGm may show a more [Pg.235]


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