Szemes

The anion coordination properties of receptors such as compound [93] (Fig. 51) are currently under investigation. This molecule contains both a redox-active ruthenium bipyridyl moiety and also a cobaltocenium unit. This type of host has already been shown by 1H nmr and fluorescence emission spectroscopy to exhibit remarkable selectivity for the chloride anion in preference to dihydrogenphosphate (Beer and Szemes, 1995). 

F Szemes, D Hesek, Z Chem, SW Dent, MGB Drew, AJ Goulden, AR Graydon, A Grieve, RJ Mortimer, T Wear, JS Weightman, PD Beer. Inorg Chem 35 5868, 1996. 

Beer, P. D., Szemes, F., Remarkable chloride over dihydrogen phosphate anion selectivity exhibited by novel macrocyclic bis [ruthenium(II) bipyridyl] and ruthenium(II) bipyridyl-metallocene receptors. J. Chem. Soc., Chem. Commun. 1995, 2245-2247. 

Beer PD, Szemes F, Passaniti P, Maestri M (2004) Inorg Chem 43 3965... 

Szemes F, Hesek D, Chen Z, Dent SW, Drew MGB, Goulden AJ, Graydon AR, Grieve A, Mortimer RJ, Wear T, Weightman JS, Beer PD (1996) Inorg Chem 35 5868... 

Beer PD, Drew MGB, Hesek D, Shade M, Szemes F (1996) Chem Commun 2161... 

Beer PD, Davis JJ, Drillsma-Milgrom DA, Szemes F (2002) Chem Commun 1716... 

Beer, P.D., Szemes, F., Passaniti, P., and Maestri, M. (2004) Luminescent ruthenium(II) bipyridine-calix[4]arene complexes as receptors for lanthanide cations. Inorganic Chemistry, 43, 3965... 

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