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Synthesis using galactose derivative starting material

In like fashion, by careful stereochemical correlation of the three masked hydroxy stereocentres in 4 [i.e. C(13), C(14) and C(15) using FK506 numbering] with various monosaccharide derivatives (Scheme 17.3), Danishefsky was able to establish an appropriate chirality match with the C(2), C(3) and C(4) stereocentres of D-galactose. Methyl p-D-galactopyranoside was therefore selected as the starting material for his synthesis of 4. [Pg.295]

The synthesis of tunicamycin V using a 2-azido-2-deoxy-D-galactose derivative as starting material for a multistep sequence has been described. ... [Pg.235]

See other pages where Synthesis using galactose derivative starting material is mentioned: [Pg.71]    [Pg.243]    [Pg.19]    [Pg.518]    [Pg.504]    [Pg.341]    [Pg.33]    [Pg.83]    [Pg.304]   
See also in sourсe #XX -- [ Pg.86 ]



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Galactose derivatives

Galactose synthesis

Material derivative

Materials synthesis

Materials use

Synthesis using galactose derivative

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