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Synthesis gilvocarcin antibiotics

A key step in the synthesis of Gilvocarcin M 713, an aryl C-glycoside antibiotic, is the regioselective cycloaddition of the aryne derived from 711 to 2-methoxyfuran, to give... [Pg.1112]

A total synthesis of both enantiomers of the C-glycoside antibiotic gilvocarcin M utilizes an 0-+C glycoside rearrangement. The natural enantiomer was thesized from D-fucose. The total synthesis of aryl C-glycoside antibiotics has been reviewed. [Pg.253]

See other pages where Synthesis gilvocarcin antibiotics is mentioned: [Pg.418] [Pg.43] [Pg.43] [Pg.155] [Pg.157] [Pg.855] [Pg.162] [Pg.105] [Pg.325] [Pg.105] [Pg.257] [Pg.53] [Pg.52] [Pg.257]

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Gilvocarcin

Gilvocarcin antibiotics

Gilvocarcins