172 sustainability Suzuki reaction

Hagiwara, H., Sugawara, Y, Hoshi, T. and Suzuki, T. (2005) Sustainable Mizoroki-Heck reaction in water remarkably high activity of Pd(OAc)2 immobilized on reversed phase silica gel with the aid of an ionic liquid. Chem. Commun., 23, 2942-4. 

Hagiwara, H., Sasaki, H., Tsubokawa, N., Hoshi, T., Suzuki, T., Tsuda, T. and Kuwabata, S., Immobilization of Pd on nanosilica dendrimer as SILC Highly active and sustainable cluster catalyst for Suzuki-Miyaura reaction, Syn. Lett. 1990-1996 (2010). 

One-pot reaction sequences comprising the Suzuki-Miyaura reaction as a key step are also common, basically, as they represent sustainable processes. Some useful recent examples include the work of Wang eta/. [157], which involved a one-pot borylation/Suzuki-Miyaura reaction. Various biaryl compounds (up to 37) were obtained in good to excellent yields. Both bromoarenes and chloroarenes were used, including heteroaryl halides. The catalyst involved was a cyclopalladated ferrocenylimine and bis(pinacolato)diboron, the boron transfer agent. The reactions were performed at 100 °C. 

F.X. (2010) Recyclable heterogeneous palladium catalysts in pure water sustainable developments in Suzuki, Heck, Sonogashira and Tsuji-Trost reactions. Adv. Synth. Catal., 352 (1), 33-79. 

In 2008, Ackerman and co-workers applied these methods for the synthesis of fully decorated triazoles [259]. Their studies revealed that a single copper system based on Cul and DMEDA L26 ligand was able to catalyze in a one-pot procedure the arylation of sodium azide and the subsequent in situ arylation in position 5 of the resulting triazole, via a sustainable C-H functionalization. Based on the same type of strategy, various organo-[l,2,3]-triazol-l-aryl-trifluoroborates were recently prepared by Ham and subsequently used as substrates in Suzuki-Miyaura cross-coupling reactions [260],... 

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