Supramolecular assemblies organotellurium

Organotellurium(II) derivatives, ArTeS2P(OR)2 (Ar = 4-MeOC6H4 or 4-EtOC6H4, R = Me or Et Ar = mesityl, R = Pr7) are supramolecular chain-like compounds, self-assembled through Te- S secondary bonds and bridging... 

Haiduc, I. Zukerman-Schpector, J. Supramolecular self-assembly through secondary bonds in organotellurium chemistry. Phosphoms Sulfur Silicon 2001. 171. 171. 

Tellurium-sulfur secondary bonds can also be a source of supramolecular selforganization [521]. These are common in organotellurium derivatives of thio-phosphorus acids. Thus, in aryltellurium(II) dimethyldithiophosphates, ArTe-[S2P(OMe)2], where Ar = Ph [522], 4-MeOC6H4 [523], and EtOQH4 [524], the molecules are assembled into chain structures, 219, via dithiophosphate bridging. 

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