Superoxometal-catalyzed co-oxidation

Fig. 17. Spectral changes accompanying the formation of benzaldehyde in the Craq002 + -catalyzed reaction between 0.11 M PhCH2OH and 0.14 mM HNO2 in 02-saturated aqueous solution at pH 1. Time interval between successive spectra is 150 s. [Craq002 + ] = 20 iM. Modified from J. Mol. Cat. A 2003, 200, 21-29, Pestovsky, O. and Bakac, A., Superoxometal-catalyzed co-oxidation of alcohols and nitrous acid with molecular oxygen , copyright (2003) with permission from Elsevier.

Scheme 15. Modified from J. Mol. Cat. A 2003, 200, 21-29, Pestovsky, O. and Bakac, A., Superoxometal-catalyzed co-oxidation of alcohols and nitrous acid with molecular oxygen , copyright (2003) with permission from Elsevier.

---