Sulfur nitride polymer

Sulfur nitride polymers [-(-S = N-)-], which have optical and electrical properties similar to those of metals, were first synthesized in 1910. These crystalline polymers, which are super-conducive at 0.25 K, may be produced at room temperature using the solid state polymerization of the dimer (S2N2). A dark blue-black amorphous paramagnetic form of poly(sulfur nitride) (structure 11.30) is produced by quenching the gaseous tetramer in liquid nitrogen. The polymer is produced on heating the tetramer to about 300°C. 

What is the ceiling temperature of sulfur nitride polymers ... 

SF3O3C, Methanesulfonate, trifluoro-metal complexes and salts, 24 243-306 (SN Sulfur nitride, polymer, 22 143 SNC, Thiocyanate... 

Polymeric sulfur nitride See sulfur nitride polymer. 

Sulfur nitride polymer (polysulfur nitride, polythiazyl) [-(SN)-]n. First synthesized in 1910 but ignored for six decades, this covalent polymer has been restudied and found to have the physical and electrical properties of a metal. It is formed by passing the vapor of (SN)4 over a catalyst that cracks it to (SN)2, which is condensed on a cold surface where it spontaneously polymerizes into crystalline form. The crystals are malleable and can be cold-worked into thin sheets or fibers under pressure, having an electrical conductivity similar to that of mercury, and superconducting near 0 K. 

Polymeric Sulfur Nitride See Sulfur Nitride Polymer. 

Sulfur Nitride Polymer n (polysulfur nitride, polythiazyl) [-(SN)-]n. First synthesized in 1910 but ignored for 6 decades, this covalent polymer has been restudied and found to have the physical and electrical... 

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