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Sulfur dioxide reactions with metal-ligand bonds

Palladium(II) complexes possessing bidentate ligands are known to efficiently catalyze the copolymerization of olefins with carbon monoxide to form polyketones.594-596 Sulfur dioxide is an attractive monomer for catalytic copolymerizations with olefins since S02, like CO, is known to undergo facile insertion reactions into a variety of transition metal-alkyl bonds. Indeed, Drent has patented alternating copolymerization of ethylene with S02 using various palladium(II) complexes.597 In 1998, Sen and coworkers also reported that [(dppp)PdMe(NCMe)]BF4 was an effective catalyst for the copolymerization of S02 with ethylene, propylene, and cyclopentene.598 There is a report of the insertion reactions of S02 into PdII-methyl bonds and the attempted spectroscopic detection of the copolymerization of ethylene and S02.599... [Pg.607]


See other pages where Sulfur dioxide reactions with metal-ligand bonds is mentioned: [Pg.1333]    [Pg.634]    [Pg.79]    [Pg.849]    [Pg.1280]    [Pg.3172]    [Pg.282]    [Pg.241]    [Pg.241]   
See also in sourсe #XX -- [ Pg.2 , Pg.2 , Pg.3 , Pg.6 , Pg.8 , Pg.8 ]




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Bonds, metal-sulfur

Dioxides, reactions

Ligands metal bonds with

Ligands metal-ligand bonds

Ligands sulfur-ligand reactions

Metal dioxides

Metal sulfur

Metal sulfurization

Metal-ligand bonding

Metal-ligand bonds

Metals metal-ligand bond

Metals metal-sulfur bond

Metal—ligand bonds reactions with

Metal—ligand bonds sulfur

Reaction with sulfur dioxide

Reactions with ligands

Sulfur bonding

Sulfur bonds

Sulfur dioxide bonding

Sulfur dioxide bonds

Sulfur dioxide metal bonds

Sulfur dioxide reactions

Sulfur dioxide reactions with metals

Sulfur ligands reactions

Sulfur reaction with

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