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Sulfur-containing compounds dioxiranes

Since dioxiranes are electrophilic oxidants, heteroatom functionalities with lone pair electrons are among the most reactive substrates towards oxidation. Among such nucleophilic heteroatom-type substrates, those that contain a nitrogen, sulfur or phosphorus atom, or a C=X functionality (where X is N or S), have been most extensively employed, mainly in view of the usefulness of the resulting oxidation products. Some less studied heteroatoms include oxygen, selenium, halogen and the metal centers in organometallic compounds. These transformations are summarized in Scheme 10. We shall present the substrate classes separately, since the heteroatom oxidation is quite substrate-dependent. [Pg.1150]

The present volume comprises 17 chapters, written by 27 authors from 11 countries, and deals with theoretical aspects and structural chemistry of peroxy compounds, with their thermochemistry, O NMR spectra and analysis, extensively with synthesis of cyclic peroxides and with the uses of peroxides in synthesis, and with peroxides in biological systems. Heterocyclic peroxides, containing silicon, germanium, sulfur and phosphorus, as well as transition metal peroxides are treated in several chapters. Special chapters deal with allylic peroxides, advances in the chemistry of dioxiranes and dioxetanes, and chemiluminescence of peroxide and with polar effects of their decomposition. A chapter on anti-malarial and anti-tumor peroxides, a hot topic in recent research of peroxides, closes the book. [Pg.1542]

The chemistries of dioxiranes in general,in addition to dimethyldioxirane (DMDO), focusing on the oxidation of sulfur compounds and heterocycles containing oxygen or sulfur,have been reviewed. Alkene epoxidation by DMDO has been studied kinetically and semi-empirically AMI calculations were used to identily the transition-state structure as the spiro conformation. ... [Pg.227]


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