Sulfur-bridged cubane-type molybdenum

SULFUR-BRIDGED CUBANE-TYPE (Mo S ) AND INCOMPLETE CUBANE-TYPE (MOjO. S. n=l-4) MOLYBDENUM AQUA IONS... [Pg.260]

Sulfur-Bridged Cubane-Type and Incomplete Cubane-Type Molybdenum Aqua Ions 261... [Pg.261]

SULFUR-BRIDGED INCOMPLETE CUBANE-TYPE MOLYBDENUM AND TUNGSTEN AQUA IONS... [Pg.144]

Sulfur-Bridged Incomplete Cubane-Type Molybdenum and Tungsten Aqua Ions 145... [Pg.145]

Each P-cluster is actually a joined pair of cubane-type clusters, one Fe4S4 and one Fe4S3 with two bridging cysteine -SH groups and one iron atom bonded to three sulfide sulfur atoms (Fig. 24-3).17/23 The FeMo-coenzyme can be released from the MoFe-protein by acid denaturation followed by extraction with dimethylformamide.24 While homocitrate was identified as a component of the isolated coenzyme, the three-dimensional structure of FeMo-co was deduced from X-ray crystallography of the intact molybdenum-iron protein.14/17/18... [Pg.1362]

Many reports on molybdenum and tungsten clusters with sulfur-bridged incomplete cubane-type cores, Msips-SXji-Sh (M = Mo,W), have appeared in the literature. The aqua ion [Mo3S4(H20)9]" (Mo3) is very useful for the... [Pg.144]

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