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Sulfonic acid amides arenes

Because C-H bonds are usually less reactive towards dioxirane oxidation than heteroatoms and C-C multiple bonds, it is instructive to give a few general guidelines on the compatibility of functional groups within the substrate to be submitted to oxidative C-H insertion Substances with low-valent heteroatoms (N, P, S, Se, I, etc.), C-C multiple bonds, and C=X groups (where X is a N or S heteroatom) are normally not suitable for C-H insertions, because these functionalities react preferably. Even heteroarenes are more susceptible to dioxirane oxidation than C-H bonds, whereas electron-rich and polycyclic arenes are only moderately tolerant, but electron-poor arenes usually resist oxidation by dioxiranes. N-oxides and N-oxyl radicals are not compatible because they catalyze the decomposition of the dioxirane. Oxygen insertion into Si-H bonds by dioxirane is more facile than into C-H bonds and, therefore, silanes are not compatible. Substance classes normally resistant towards dioxirane oxidation include the carboxylic acids and their derivatives (anhydrides, esters, amides, and nitriles), sulfonic acids and their de-... [Pg.513]


See other pages where Sulfonic acid amides arenes is mentioned: [Pg.95]    [Pg.95]    [Pg.95]    [Pg.95]    [Pg.28]    [Pg.9]    [Pg.9]    [Pg.83]    [Pg.611]    [Pg.618]    [Pg.848]    [Pg.401]    [Pg.83]    [Pg.439]   
See also in sourсe #XX -- [ Pg.18 , Pg.473 ]




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Amide sulfon

Amides sulfonated

Arenes amidation

Arenes sulfonation

Sulfonated arene

Sulfonic acid amides

Sulfonic acid amides sulfonates

Sulfonic acid amides sulfones

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