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Sugars chain-lengthening

Rosanoff in 1906 selected the enantiomeric glyceraldehydes as the point of reference any sugar derivable by chain lengthening from what is now known as D-glyceraldehyde belongs to the D series, a convention still in use. [Pg.48]

Kiliani-Fischer synthesis Chain lengthening of. sugars through a cyanohydrin intermediate. [Pg.259]

Ketose A sugar based on ketones—so that a three-carbon chain would be a ketotriose, for example. Kiliani-Fischer synthesis An older method for chain lengthening of sugars through a cyanohydrin... [Pg.512]

Larger sugars can be made from smaller ones and vice versa, by chain lengthening and chain shortening. These transformations can also be used to structurally correlate various sugars, a procedure applied by Fischer to prove the relative configuration of all the stereocenters in the aldoses shown in Figure 24-1. [Pg.1092]

In Summary Sugars can be made from other sugars by step-by-step one-carbon chain lengthening (cyanohydrin formation and reduction) or shortening (Ruff degradation). [Pg.1095]

The sugar chain can be lengthened (Killani-Fischer reaction) or shortened (Wohl or Ruff degradations. [Pg.769]

Kiliani-Fischer synthesis (Section 25.6) A method for lengthening the chain of an aldose sugar. [Pg.1244]

See other pages where Sugars chain-lengthening is mentioned: [Pg.994]    [Pg.233]    [Pg.101]    [Pg.22]    [Pg.1125]    [Pg.994]    [Pg.191]    [Pg.4]    [Pg.1049]    [Pg.1069]    [Pg.994]    [Pg.323]    [Pg.323]    [Pg.1049]    [Pg.492]    [Pg.4]    [Pg.457]    [Pg.1121]    [Pg.74]    [Pg.185]    [Pg.108]    [Pg.69]    [Pg.1022]    [Pg.1116]    [Pg.323]    [Pg.200]    [Pg.374]    [Pg.397]    [Pg.282]    [Pg.211]    [Pg.291]    [Pg.244]    [Pg.1047]    [Pg.60]    [Pg.105]    [Pg.107]    [Pg.312]    [Pg.18]   
See also in sourсe #XX -- [ Pg.1125 , Pg.1126 ]



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Chain lengthening

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