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Substitution reactions asymmetric, with zinc compounds

Asymmetric phosphines, polymer-supported, 12, 701 Asymmetric pinacol coupling reactions, characteristics, 11, 48 Asymmetric reactions, with allylic tins, 9, 355 Asymmetric substitution reactions, with zinc compounds, 9,99 Atmosphere studies... [Pg.59]

The use of inorganic supramolecular compounds in catalysis has also been successful in recent years. Hupp etal. incorporated a Mn(IIl)-porphyrm (see Porphyrin) epoxidation catalyst inside a molecular square, a system that shows enhanced catalyst stabihty and substrate selectivity as compared to the free catalyst. In another example, chiral metaUocyclophanes were constructed from Pt(PEt3)2 units and enantiopme atropoisomeric t,t -binapthyl-6,6 -bis-(acetylenes) and used in enantioselective diethyl zinc addition to aldehydes to afford chiral secondary alcohols. The first organometaUic triangle based on Pt(II) and alkyne-di-substituted-binaphfhyl system was reported and found to effect asymmetric catalysis reactions of aldehydes to alcohols with excellent conversion rates and enantiomeric excess/ ... [Pg.5723]

See other pages where Substitution reactions asymmetric, with zinc compounds is mentioned: [Pg.133]    [Pg.133]    [Pg.190]    [Pg.58]    [Pg.221]    [Pg.221]    [Pg.190]    [Pg.44]    [Pg.972]    [Pg.38]    [Pg.1120]    [Pg.76]    [Pg.74]    [Pg.183]    [Pg.311]    [Pg.107]    [Pg.9]    [Pg.139]    [Pg.324]    [Pg.352]    [Pg.345]    [Pg.146]   
See also in sourсe #XX -- [ Pg.9 , Pg.99 ]



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Asymmetric substitution reactions

Substituted Compounds

Substituted reaction with

Substitution compounds

Substitution reactions with zinc compounds

With zinc

Zinc compounds

Zinc compounds reactions

Zinc reaction

Zinc-substituted

Zincs reactions with

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