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Subject polarization energies

More interesting is the use of nonpolar solvents (e. g. xylene, toluene, carbon tetrachloride, hydrocarbons), because these are transparent to MW and absorb them only weakly. They therefore enable specific absorption by the reactants. If these reactants are polar, energy transfer occurs from the reactants to the solvent and the results might be different under the action of MW and A. This effect seems to be clearly dependent on the reaction and is, therefore, the subject of controversy. In xylene under reflux, for example, no MW-specific effects were observed for the Diels-Alder reaction [5] whereas important specific effects were described for aryldiazepinone synthesis [33]. [Pg.67]

The position of energy level is subjected to fluctuations, whereas that of level 8 is independent of solvent polarization. [Pg.647]


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See also in sourсe #XX -- [ Pg.358 ]




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