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Subject molecular propagation

It should be noted that in the literature the term single-file diffusion has sometimes been used to indicate only the mutual steric hindrance of the molecules in zeolite channels and not the additional constraint of an absolute exclusion of their mutual passage. Such terminology is clearly misleading since in this case molecular propagation would also be subjected to Pick s laws. [Pg.332]

Like any other protein, the molecular structure of the prion is subject to conformational flexibility and to various thermal-induced fluctuations between varying conformational states. However, if these fluctuations permit the PrP conformation to be attained, then this abnormal conformer promotes the widespread conversion of PrP to PrP , leading to the precipitous deposition of the abnormal protein throughout the brain (mirrored by the rapid and relentlessly downhill clinical course). This pathological self-propagating shape conversion of a-helical PrP to P-sheet PrP may in principle be initiated by a seed PrP molecule in the neurotoxic conformation. This explains the transmissibility of prion diseases and accounts for how susceptible humans exposed to beef from an animal with mad cow disease develop variant Creutzfeldt-Jakob disease. [Pg.515]

The mechanisms behind lipid oxidation of foods has been the subject of many research projects. One reaction in particular, autoxida-tion, is consistently believed to be the major source of lipid oxidation in foods (Fennema, 1993). Autoxidation involves self-catalytic reactions with molecular oxygen in which free radicals are formed from unsaturated fatty acids (initiation), followed by reaction with oxygen to form peroxy radicals (propagation), and terminated by reactions with other unsaturated molecules to form hydroperoxides (termination O Connor and O Brien, 1994). Additionally, enzymes inherent in the food system can contribute to lipid oxidization. [Pg.535]

Motivated by the remarkable discovery of quasicrystalline ordering in solids in 1984 [1], wave propagation in deterministic non periodic media has been an area of intense research. Following the successful experimental realisation of a multitude of such structures through modem technologies, such as molecular beam epitaxy and laser ablation [2], their interest has increased ever since. The most widely known examples are quasi-periodic structures obtained by substitution rules, such as Fibonacci- or Thue-Morse-chains [3,4], Much less has been published on quasi-periodic chains constructed according to a Cantor-set algorithm, which are the subject of this note. [Pg.44]


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See also in sourсe #XX -- [ Pg.91 ]




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Propagation Subject

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