0-Styrenesulfonyl chloride

Sommelet reaction, 33, 93 Sorbic acid, 5-hydroxy-/3-methyl, J-lactone, 32, 57 Stannic chloride, 33, 91 Stearic acid, 34, 15 Stearone, 33, 84 cis-Stilbene, 33, 88 fraws-Stilbene, 33, 89 Stirrer, for caustic fusion, 30, 104, 105 seal for, 30, 54 Stobbe condensation, 30, 18 Styrene, 33, 72 34, 85 reaction with sulfuric acid, 35, 83 Styrene dibromide, 30, 73 Styrene oxide, 31, 3 0-Styrenesulfonyl chloride, 34, 85 Succinic acid, 34, 44 Succinic acid, < -benzhydrylidene-, a-ETHYL ESTER, 30, 18 CLNNAMYL-, 31, 85 DIPHENYL ESTER, 34, 44 HEPTANOYL-, DIETHYL ESTER, 34, 51 PHENYL-, 30, 83 Succinic anhydride, 34, 40 SUCCINONITRILE, a, -DIPHENYL-, 32, 63 Sulfide, methyl 2-thienyl, 35, 85 Sulfonation of styrene, 34, 85 Sulfonyl chloride, from sodium sulfonate, 34, 85... 

Styrenesulfonyl chloride (11.6 g, 5.16 x 10-2 mol) was mixed with toluene (20.0 mL) and benzyltriethylammonium chloride (0.74 g, 3.99 x 10 3 mol) and cooled to 0 °C. A 5.5 mL aliquot of 35 wt% NaOH was added, and 3-ethyl-3-oxetanemethanol (5.0 g, 4.30 X 10 2 mol) was added dropwise to the solution and kept at 0 °C for 24 h. The organic phase was separated and washed with saturated sodium bicarbonate solution and then with water. The organic layer was dried over anhydrous MgS04. The product was purified by column... 

Preparation of 1,2,3,4-tetrahydro-l-naphthylideneamino p-slyrenesulfonate (NISS) To a solution of 1-tetralone oxime (13.7g, 0.085 mol) in pyridine (32 ml.) below 10 °C was slowly added p-styrenesulfonyl chloride (19g, 0.094 mol), whidi was freshly prepared from potassium p-styrenesulfonate and PClj according to the method reported ly Iwakura et al (15). The reaction was continued with... 

---