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Structure with substituted carbonyl clusters

In 1962, Dahl had also structurally characterized Fej(CO)i5C, the first high nuclearity carbide (26). This compound was originally prepared in extremely low yields (0.5%) by the reaction of Fe3(CO)i2 with substituted acetylenes, and, probably due to the peculiarity of this synthesis, was considered for some time much more a curiosity rather than being recognized as the precursor of today s large family of carbide-carbonyl clusters. [Pg.286]

Ni(CO)4 -H 4 PCCHaCHaCNla Ni4(CO)6[P(CH2CH2Clsr)3]4 -H 10 CO (27) The carbonyl clusters substituted by ligands with Group V donor atoms are listed in Table V along with their preparations and references to structural studies. [Pg.487]

See other pages where Structure with substituted carbonyl clusters is mentioned: [Pg.220]    [Pg.13]    [Pg.349]    [Pg.52]    [Pg.30]    [Pg.89]    [Pg.30]    [Pg.350]    [Pg.242]    [Pg.46]    [Pg.997]    [Pg.17]    [Pg.201]    [Pg.209]    [Pg.210]    [Pg.156]    [Pg.510]    [Pg.289]    [Pg.340]    [Pg.150]    [Pg.171]    [Pg.172]    [Pg.137]    [Pg.154]    [Pg.424]    [Pg.61]    [Pg.147]    [Pg.177]    [Pg.438]    [Pg.404]    [Pg.219]    [Pg.335]    [Pg.656]    [Pg.301]    [Pg.339]    [Pg.7]    [Pg.32]    [Pg.55]    [Pg.151]    [Pg.25]    [Pg.674]    [Pg.29]    [Pg.31]    [Pg.57]    [Pg.110]    [Pg.24]    [Pg.341]   
See also in sourсe #XX -- [ Pg.13 ]



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Carbonyl clusters

Carbonyl clusters substituted

Carbonyl substitution

Carbonylation substitutive

Carbonyls structure

Cluster structures

Structures Clustering

Substitution structure

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