Strontium chromate, precipitation

Strontium Chromate. Strontium chromate [7789-06-2] SrCrO, is made by precipitation of a water-soluble chromate solution using a strontium salt or of chromic acid using a strontium hydroxide solution. It has a specific gravity of 3.84 and is used as alow toxicity, yellow pigment and as an anticorrosive primer for zinc, magnesium, alurninum, and alloys used in aircraft manufacture (8) (see Corrosion and corrosion control). 

The classical analytical method of deterruination of barium ion is gravimetric, by precipitating and weighing insoluble barium sulfate. Barium chromate, which is more insoluble than strontium chromate in a slightly acidic solution, gives a fairly good separation of the two elements. 

Precipitation reactions, like all reactions, reach a position of equilibrium. Suppose, for example, solutions of Sr(N03)2 and K2Cr04 are mixed. In this case, Sr2+ ions combine with Cr042- ions to form a yellow precipitate of strontium chromate, SrCr04 (Figure 16.1). Very quickly, an equilibrium is established between the solid and the corresponding ions in solution ... 

In the laboratory, strontium chromate (Ksp = 3.6 X 10-5) can be prepared by mixing solutions containing strontium ions and chromate ions, where the concentrations of these ions are high enough to form a precipitate. Decide whether a precipitate will form when... 

Strontium Chromate. Strontium chromate is precipitated from solutions of sodium dichromate and strontium chloride, followed by filtration, washing, drying, and grinding. A primer composition based on strontium and calcium chromates is described in [5.70], [5.118]. 

Strontium chromate, [CAS 7789-06-2], SrCr04, yellow precipitate (Kjp = 3.75 y 10 ) fonncd by reaction of strontium salt solution and potassium chromate solution. 

White precipitate of strontium carbonate White precipitate of strontium sulfate White precipitate of strontium sulfate Yellow precipitate of strontium chromate White precipitate of strontium oxalate, which is soluble in mineral acids... 

Yellow precipitate of strontium chromate, which is soluble in mineral acids... 

Sodium rhodizonate reagent reddish-brown precipitate of strontium rhodi-zonate in neutral solution. The test is applied to the elements of Group IV. Barium reacts similarly and a method for the detection of barium in the presence of strontium has already been described (Section III.31, reaction 7). To detect strontium in the presence of barium, the latter is converted into the insoluble barium chromate. Barium chromate does not react with sodium rhodizonate, but the more soluble strontium chromate reacts normally. 

Strontium Dichromate, SrCrjO. SHjO, is formed by dissolving the normal chromate in chromic acid solution and allowing to crystallise, or by treating freshly precipitated strontium chromate with solid chromic anhydride. It yields large reddish-brown monoclinic crystals,... 

The pH can also be controlled by evaporation of ammonia. For example, barium chromate can be precipitated in the presence of strontium and lead by first complexing the metal ions at a pH of 10.4, followed by evaporation of ammonia. The pH decreases slowly, and barium chromate precipitates since the barium ion is no longer complexed at the lower pH. ... 

When a soln. of strontium chloride is treated with potassium chromate, strontium chromate, SrCr04, is precipitated. J. D. Smith observed that no precipitation occurs with dil. soln. J. W. Dobereiner, that aq. soln. of strontium hydroxide gave no precipitate and H. Kammerer, and F. T. Frerichs, that no precipitation occurs if the soln. be acidified with acetic acid, but H. Caron and D. A. Raquet found that if the soln. be neutralized with ammonia, and treated with alcohol, strontium chromate is precipitated. A. de Schulten obtained the crystalhne... 

Ruff and E. Asoher studied the joint precipitation of lead and barium chromates barium and strontium chromates and barium sulphate and chromate and... 

After strontium carrier is added to a small volume (<10 ml) of °Sr solution, sufficient fuming nitric acid is added to attain a nitric acid concentration of 14-16 N. The solution with strontium nitrate precipitate is cooled in an ice bath and then centrifuged. The supernatant solution is thoroughly decanted and the strontium nitrate precipitate is dissolved in water. Barium and yttrium carriers are added. Precipitation of barium chromate at pH 5.5 removes and natural radium from the supernatant strontium solution (for counting, if needed, of these two separated radioelements). Precipitation of yttrium hydroxide in basic solution then removes the daughter that has grown into the °Sr parent. Ammonium oxalate is immediately added to the supernatant solution to precipitate strontium oxalate. The precipitate is washed and dried in the filter holder with alcohol and ether, promptly weighed for yield determination, and counted with a beta-particle detector (Chieco 1997) such as a proportional detector. 

These results reveal that as the solution of K2Cr04 is slowly added to the solution of Ba and Sr, barium chromate begins to precipitate when the Cr04 concentration reaches 1.2 X 10 M. Barium chromate continues to precipitate as K2Cr04 is added. When the concentration of Cr04 reaches 3.5 X 10 M, strontium chromate begins to precipitate. 

What must be the concentration of chromate ion in order to precipitate strontium chromate, SrCr04, from a solution that is0.0025MSr A p for strontium chromate is3.5 X 10. ... 

Among the alkaline earth metals, only barium and strontium salts react in neutral solution with sodium rhodizonate (see page 119) they form brown-red precipitates. To detect strontium in the presence of barium, the latter must therefore be converted into a compound which does not react with sodium rhodizonate. Insoluble barium chromate is suitable, since strontium chromate is sufficiently soluble in water to react normally with sodium rhodizonate. 

Exercise 9 Let s consider a solution containing Ba and Sr + ions, both at concentrations 10" mol/L. A 10 mol/L chromate solution is added. Determine the pH limits between which its value must be located for barium chromate to be precipitated at the 0.1% level without any precipitation of strontium chromate [fi s(BaCr04) = 10- Ts(SrCr04) = IQ-, iiTaCHCrO ) =... 

At pH < 2.70, barium chromate does not precipitate quantitatively. At pH > 5.02, strontium chromate begins to precipitate. 

Figure 15.3 Precipitation of strontium chromate. A solution prepared by mixing solutions of Sr(N03)2 and K2Cr04 is in equilibrium with yellow SrCr04(s). In such a solution [Sr2+] X [Cr042-] = 3.6 x 10 k...

An outline of the method used for determination of radiostrontium in various materials by nitrate precipitation is as follows. The ashed material is dissolved in nitric acid in the presence of strontium and barium carriers. The nitric acid concentration is then increased to precipitate all the strontium and barium (and part of the calcium) as nitrates. After further nitric acid separations, barium chromate and iron hydroxide scavenges are carried out. The subsequent treatment depends somewhat on the circumstances but the following is normal practice. 

Traces of Sr have been co-precipitated as the chromate with Ba [31] and as the oxalate with Ca [32]. Enrichment of strontium on Mn02aq. has also been utilized [33]. 

Why are strontium ions, rather than barium ions, chosen to precipitate the chromate ... 

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