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Strong field configurations

For the cubic-field (octahedral or tetrahedral) subshells g(g), there is spatial degeneracy for e(g) but not for eQy Nevertheless, neither of these configurations give rise to an orbital contribution to the magnetic moment. The conditions for orbital contributions to arise in strong-field configurations are that the orbitals must be... [Pg.93]

The irreducible representations arising from any strong field configuration for a given dx system may readily be obtained from the listed headings of the columns of the repulsion matrices of Tables 3—6, e.g. d2, (n8) -> 11 + d + 3II + 3. [Pg.58]

Free- ion terms Weak crystal field Intermediate crystal field Strong- field terms Strong-field configurations... [Pg.269]

For a given parent infinitely- strong field configuration the order of states is unchanged... [Pg.300]

Figure 10 Free-ion term—strong-field configuration correlation diagrams for octahedral and tetrahedral stereochemistries (a) tfi and Figure 10 Free-ion term—strong-field configuration correlation diagrams for octahedral and tetrahedral stereochemistries (a) tfi and <F, (b) d- and tf, (c) and tfi and (d) cfi...
See text for definition of t, A and A. The terms arise from the strong-field configurations ... [Pg.264]

See other pages where Strong field configurations is mentioned: [Pg.35]    [Pg.48]    [Pg.50]    [Pg.50]    [Pg.71]    [Pg.77]    [Pg.79]    [Pg.92]    [Pg.93]    [Pg.136]    [Pg.54]    [Pg.98]    [Pg.263]    [Pg.263]    [Pg.264]    [Pg.266]    [Pg.268]    [Pg.268]    [Pg.268]    [Pg.763]    [Pg.239]    [Pg.248]    [Pg.262]    [Pg.262]    [Pg.266]    [Pg.262]    [Pg.127]    [Pg.279]    [Pg.84]    [Pg.143]    [Pg.144]    [Pg.144]    [Pg.144]    [Pg.301]    [Pg.301]    [Pg.763]    [Pg.341]    [Pg.753]    [Pg.88]    [Pg.114]    [Pg.142]    [Pg.142]    [Pg.143]    [Pg.144]   
See also in sourсe #XX -- [ Pg.341 ]



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