Streptavidin vanadyl-loaded

Enantioselective Sulfoxidation Based on Vanadyl-loaded Streptavidin... 

Figure 13.9 Substrates and operating conditions used for sulfoxidation catalyzed by artificial metalloenzymes based on vanadyl-loaded streptavidin. Reprinted with permission of Swiss Chemical Society...

A. Pordea, M. Creus, J. Panek, C. Duboc, M. Novic, D. Mathis, T. R. Ward, Artificial metal-loenzyme for enantioselective sulfoxidation based on vanadyl-loaded streptavidin, J. Am. Chem. Soc., 2008, 130, 8085-8088. 

Artificial metalloenzymes based on vanadyl-loaded streptavidin was used for catalytic enantioselective sulfoxidation with f-butyl hydroperoxide [70]. Incorporation of a vanadyl ion into the biotin-binding pocket of streptavidin resulted in a catalyst that transformed both dialkyl and alkyl-aryl sulfides to their sulfoxides in high ee. 

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See also in sourсe #XX -- [ ]

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