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Enantioselective Sulfoxidation Based on Vanadyl-loaded Streptavidin

6 Enantioselective Sulfoxidation Based on Vanadyl-loaded Streptavidin [Pg.372]

Addition of vanadyl sulfate to Sav affords an artificial oxidase for the sulfoxidation of [Pg.372]

A. Pordea, M. Creus, J. Panek, C. Duboc, M. Novic, D. Mathis, T. R. Ward, Artificial metal-loenzyme for enantioselective sulfoxidation based on vanadyl-loaded streptavidin, J. Am. Chem. Soc., 2008, 130, 8085-8088. [Pg.374]



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Base-load

Enantioselective sulfoxidation

Enantioselective sulfoxide

Enantioselectivity sulfoxidation

Streptavidin

Streptavidin vanadyl-loaded

Vanadyl

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